Curriculum Vitaes

Dai shirotani

  (城谷 大)

Profile Information

Affiliation
Institute of Education Center of Advanced Education, Osaka Sangyo University
Degree
博士(理学)(Mar, 2010, 大阪大学)

J-GLOBAL ID
201301098530870350
researchmap Member ID
B000231984

Research Interests

 3

Education

 3

Papers

 10
  • Sumio Kaizaki, Dai Shirotani, Keiko Toya, Masako Iwamatsu, Yumiko Kato, Mikiko Maki, Takanori Hirami, Hiroshi Seki, Hiroyasu Nakata, Hisako Sato
    JOURNAL OF CERAMIC PROCESSING RESEARCH, 17(5) 464-467, May, 2016  Peer-reviewed
    This paper concerns with the synthesis and the luminescence spectra of lanthanide complexes of EuIII) and/or Eu(II) or Tb(III) ions which are embedded into fibrous palygorskite and sepiolite clays in which the magnesium ion are ion exchanged with lanthanide ions. The He-Cd laser excitation photoluminescence of the present complexes without organic ligands exhibit the deferration effects. The phosphors with light harvesting ligands such as benzophenone derivatives and 1,10-phenanthroline give the fairly strong visible luminescence by UV-A light excitation with a LED black light in a light room under fluorescent lamps. Further, the temperature dependent phosphors with benzophenone derivatives exhibit the stronger luminescence with increasing the temperature over 100 degrees C.
  • Sumio Kaizaki, Dai Shirotani, Hisako Sato
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 15(24) 9513-9515, 2013  Peer-reviewed
    For Delta-SAPR-8-Cs[Ln((+)-hfbc)(4)]((+)-hfbc = (+)-heptafluoro-butyryl-camphorate; Cs-Ln), the vibrational circular dichroism pattern and intensity of Cs-La, Cs-Nd, Cs-Gd, Cs-Ho, Cs-Er, Cs-Lu and Cs-Sm, Cs-Eu, Cs-Tb, Cs-Dy, Cs-Tm, Cs-Yb, respectively, are correlated with the even and the odd parity of total orbital angular momentum in the ground state terms.
  • Dai Shirotani, Kazuaki Yamanari, Reiko Kuroda, Takunori Harada, Jamie L. Lunkley, Gilles Muller, Hisako Sato, Sumio Kaizaki
    CHIRALITY, 24(12) 1055-1062, Dec, 2012  Peer-reviewed
    The preparation of tetrakis((+)-hfbc) lanthanide(III) complexes with an encapsulated alkali metal and ammonium ions M[Ln((+)-hfbc)4] (hereafter abbreviated as M-Ln?:?(+)-hfbc, (+)-heptafluorobutyrylcamphorate; M, ammonium or benzyl ammonium ions as well as alkali metal ions) was reported and discussed. The electronic circular dichroism (CD) spectra in the intraligand p-p* transition of MLn were examined in view of the solvent effect. Here, the concentration, alkali metal, and ammonium ion dependences are compared with the solid CD, 5D0???7F0(Eu(III)) excitation spectra, circularly polarized luminescence, and vibrational circular dichroism. It has been revealed that the dodecahedral eight coordinate DD-8-M-Ln complexes in crystals are equilibrated between the diastereoselectively formed square antiprism eight coordinate SAPR-8-M-Ln and [Ln((+)-hfbc)3] in EtOH and CH3CN solutions or between the SAPR-8-M-Ln and DD-D2d(mmmm)-8-M-Ln complexes in CHCl3 solution. The observed CD couplets are found to reflect the exciton CD couplets which are useful to determine the four-bladed SAPR-(llll) absolute configuration around the lanthanide(III) ion. Chirality 24:10551062, 2012. (c) 2012 Wiley Periodicals, Inc.
  • Dai Shirotani, Hisako Sato, Kazuaki Yamanari, Sumio Kaizaki
    DALTON TRANSACTIONS, 41(35) 10557-10567, 2012  Peer-reviewed
    For electronic circular dichroism in the 4f-4f transitions (4f-4f CD) of a series of nine tetrakis ((+)-3-heptafluorobutyrylcamphorato) Ln(III) complexes,Delta-SAPR-8-C-4(llll) Cs[Ln((+)-hfbc)(4)]center dot H2O (Cs-Ln = Cs-Pr, -Nd, -Sm, -Eu, -Dy, -Ho, -Er, -Tm, -Yb), the spectroscopic observables such as the dissymmetry factor g = Delta epsilon/epsilon values with the intensities (Delta epsilon) of the CD components and the molar absorption intensities (epsilon) in the 4f-4f transitions between the L-2S+1(J) levels are compared with each other to test the classification of the CD components in the relative order of the observables predicted in terms of the selection rule for 4f-4f transitions. The 4f-4f CD-based chiroptical spectra-structural relationship across the series of Delta-SAPR-8-C-4(llll) lanthanide(III) complexes is proposed: the signs of the 4f-4f CD or CPL in the hypersensitive transitions are related to the absolute configuration; Ln complexes with a negative CD component have the Delta-configuration around Ln(III) and vice versa.
  • Jamie L. Lunkley, Dai Shirotani, Kazuaki Yamanari, Sumio Kaizaki, Gilles Muller
    INORGANIC CHEMISTRY, 50(24) 12724-12732, Dec, 2011  Peer-reviewed
    The luminescence and circularly polarized luminescence (CPL) spectra of M-I[Eu((+)-hfbc)(4)] show a similar behavior to the exciton CD in the intraligand pi-pi* transitions when the alkali metal ions and solvents are manipulated. There is a difference in susceptibility in solvation toward the alkali metal ions but not toward the Eu(III) ion, as in the case of axially symmetric DOTA-type compounds. The remarkable CPL in the 4f-4f transitions provide much more information on the stereospecific formation of chiral Eu(111) complexes, since CPL spectroscopy is limited to luminescent species and reflects selectively toward helicity of the local structural environment around the lanthanide(III). While in comparison, exciton CD reveals the chiral structural information from the helical arrangement of the four bladed chelates. Of special importance, the observation of the highest CPL activities measured to date for lanthanide(III)-containing compounds (i.e., Eu and Sm) in solution supports the theory that the chirality of lanthanide(III) in the excited state corresponds to that in the ground state, which was derived from the exciton CD.
  • Hisako Sato, Dai Shirotani, Kazuaki Yamanari, Sumio Kaizaki
    INORGANIC CHEMISTRY, 49(2) 356-358, Jan, 2010  Peer-reviewed
    The vibrational circular dichroism (VCD) spectra for Delta-M[Ln((+)-hfbC)(4)] (M(I) = Na, K, Rb, Cs; Ln(III) = La, tu; abbreviated as M-Ln) and Delta-Cs[Yb((+)-hfbC)(4)] (Cs-Yb) were observed in CDCl(3) solutions. The VCD signs and/or intensities are mostly different from those of the Delta-tris(beta-diketonato) transition-metal complexes. The M-Ln complexes give the strong VCD peak(s) near 1550 cm(-1). These VCD patterns are different from each lanthanide(III) complex, but their intensities change with variation of the alkali metal ion. A positive-negative couplet VCD near 1550 cm(-1) for the Delta-M-La complexes is observed similarly for the Delta-tris(beta-diketonato) complexes, confirming the assignment to the Delta absolute configuration based on the exciton CD. The density functional theory calculated VCD for the two peaks at 1650 and 1550 cm(-1) reproduces the relative intensity and signs of the observed ones for the Delta center dot M-La(III) complexes.
  • Jamie L. Lunkley, Dai Shirotani, Kazuaki Yamanari, Sumio Kaizaki, Gilles Muller
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130(42) 13814-13815, Oct, 2008  Peer-reviewed
    The largest CPL activity ever measured was observed for cesium tetrakis(3-heptafluoro-butylryl-(+)-camphorato) Eu(III) complexes in EtOH and CHCl3 solutions substantiating the stereospecific formation of chiral Delta-SAPR-(C-4) configuration with the aid of Cs+ center dot center dot center dot FC (fluorocarbon) interactions more clearly than the exciton CD spectra.
  • Dai Shirotani, Takayoshi Suzuki, Kazuaki Yamanari, Sumio Kaizaki
    JOURNAL OF ALLOYS AND COMPOUNDS, 451(1-2) 325-328, Feb, 2008  Peer-reviewed
    The X-ray crystal structure of tetrakis (+)-hfbc Pr(III) complex, Na[Pr((+)-hfbc)(4)]center dot CH3CN, was compared with that of the corresponding Na-La complex with a pseudo-achiral dodecahedron, and the solution CD spectra were also discussed in the 4f-4f transition in consideration of the exciton CD couplet showing Delta-SAPR-8 configuration in CHCl3. (c) 2007 Published by Elsevier B.V.
  • Dai Shirotani, Takayoshi Suzuki, Sumio Kaizaki
    INORGANIC CHEMISTRY, 45(16) 6111-6113, Aug, 2006  Peer-reviewed
    For newly prepared sodium tetrakis( 3-heptafluorobutylryl-( +)-camphorato) Ln( III) complexes, the X-ray crystal analysis revealed an unprecedented pseudo-achiral dodecahedron ( DD-8 ( D-2d)), whereas in CHCl3 solution, the exciton CD and F-19 NMR spectra showed a novel chiral Delta-SAPR-8 ( C-4) configuration which is stereospecifically formed by a trapped Na+ ion with Na+center dot center dot center dot FC ( fluorocarbon) interactions.
  • S Kaizaki, D Shirotani, Y Tsukahara, H Nakata
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (17) 3503-3505, Sep, 2005  Peer-reviewed
    This study demonstrates the first observation of energy transfer from the doublet state of the nitronyl nitroxide radical ligand in Ln(III) complexes, exerting the light-harvesting antenna effect on the NIR luminescence for the first time. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

Misc.

 15

Research Projects

 1