Center of Advanced Education

城谷 大

シロタニ ダイ  (Dai shirotani)

基本情報

所属
大阪産業大学 全学教育機構 高等教育センター 講師
学位
博士(理学)(2010年3月 大阪大学)

J-GLOBAL ID
201301098530870350
researchmap会員ID
B000231984

研究キーワード

 3

論文

 10
  • Sumio Kaizaki, Dai Shirotani, Keiko Toya, Masako Iwamatsu, Yumiko Kato, Mikiko Maki, Takanori Hirami, Hiroshi Seki, Hiroyasu Nakata, Hisako Sato
    JOURNAL OF CERAMIC PROCESSING RESEARCH 17(5) 464-467 2016年5月  査読有り
    This paper concerns with the synthesis and the luminescence spectra of lanthanide complexes of EuIII) and/or Eu(II) or Tb(III) ions which are embedded into fibrous palygorskite and sepiolite clays in which the magnesium ion are ion exchanged with lanthanide ions. The He-Cd laser excitation photoluminescence of the present complexes without organic ligands exhibit the deferration effects. The phosphors with light harvesting ligands such as benzophenone derivatives and 1,10-phenanthroline give the fairly strong visible luminescence by UV-A light excitation with a LED black light in a light room under fluorescent lamps. Further, the temperature dependent phosphors with benzophenone derivatives exhibit the stronger luminescence with increasing the temperature over 100 degrees C.
  • Dai Shirotani, Kazuaki Yamanari, Reiko Kuroda, Takunori Harada, Jamie L. Lunkley, Gilles Muller, Hisako Sato, Sumio Kaizaki
    CHIRALITY 24(12) 1055-1062 2012年12月  査読有り
    The preparation of tetrakis((+)-hfbc) lanthanide(III) complexes with an encapsulated alkali metal and ammonium ions M[Ln((+)-hfbc)4] (hereafter abbreviated as M-Ln?:?(+)-hfbc, (+)-heptafluorobutyrylcamphorate; M, ammonium or benzyl ammonium ions as well as alkali metal ions) was reported and discussed. The electronic circular dichroism (CD) spectra in the intraligand p-p* transition of MLn were examined in view of the solvent effect. Here, the concentration, alkali metal, and ammonium ion dependences are compared with the solid CD, 5D0???7F0(Eu(III)) excitation spectra, circularly polarized luminescence, and vibrational circular dichroism. It has been revealed that the dodecahedral eight coordinate DD-8-M-Ln complexes in crystals are equilibrated between the diastereoselectively formed square antiprism eight coordinate SAPR-8-M-Ln and [Ln((+)-hfbc)3] in EtOH and CH3CN solutions or between the SAPR-8-M-Ln and DD-D2d(mmmm)-8-M-Ln complexes in CHCl3 solution. The observed CD couplets are found to reflect the exciton CD couplets which are useful to determine the four-bladed SAPR-(llll) absolute configuration around the lanthanide(III) ion. Chirality 24:10551062, 2012. (c) 2012 Wiley Periodicals, Inc.
  • Dai Shirotani, Hisako Sato, Kazuaki Yamanari, Sumio Kaizaki
    DALTON TRANSACTIONS 41(35) 10557-10567 2012年  査読有り
    For electronic circular dichroism in the 4f-4f transitions (4f-4f CD) of a series of nine tetrakis ((+)-3-heptafluorobutyrylcamphorato) Ln(III) complexes,Delta-SAPR-8-C-4(llll) Cs[Ln((+)-hfbc)(4)]center dot H2O (Cs-Ln = Cs-Pr, -Nd, -Sm, -Eu, -Dy, -Ho, -Er, -Tm, -Yb), the spectroscopic observables such as the dissymmetry factor g = Delta epsilon/epsilon values with the intensities (Delta epsilon) of the CD components and the molar absorption intensities (epsilon) in the 4f-4f transitions between the L-2S+1(J) levels are compared with each other to test the classification of the CD components in the relative order of the observables predicted in terms of the selection rule for 4f-4f transitions. The 4f-4f CD-based chiroptical spectra-structural relationship across the series of Delta-SAPR-8-C-4(llll) lanthanide(III) complexes is proposed: the signs of the 4f-4f CD or CPL in the hypersensitive transitions are related to the absolute configuration; Ln complexes with a negative CD component have the Delta-configuration around Ln(III) and vice versa.
  • Jamie L. Lunkley, Dai Shirotani, Kazuaki Yamanari, Sumio Kaizaki, Gilles Muller
    INORGANIC CHEMISTRY 50(24) 12724-12732 2011年12月  査読有り
    The luminescence and circularly polarized luminescence (CPL) spectra of M-I[Eu((+)-hfbc)(4)] show a similar behavior to the exciton CD in the intraligand pi-pi* transitions when the alkali metal ions and solvents are manipulated. There is a difference in susceptibility in solvation toward the alkali metal ions but not toward the Eu(III) ion, as in the case of axially symmetric DOTA-type compounds. The remarkable CPL in the 4f-4f transitions provide much more information on the stereospecific formation of chiral Eu(111) complexes, since CPL spectroscopy is limited to luminescent species and reflects selectively toward helicity of the local structural environment around the lanthanide(III). While in comparison, exciton CD reveals the chiral structural information from the helical arrangement of the four bladed chelates. Of special importance, the observation of the highest CPL activities measured to date for lanthanide(III)-containing compounds (i.e., Eu and Sm) in solution supports the theory that the chirality of lanthanide(III) in the excited state corresponds to that in the ground state, which was derived from the exciton CD.

MISC

 15

共同研究・競争的資金等の研究課題

 1