田川 由美子

The detergency of polyethylene terephthalate (PET) films in an aqueous solution was investigated using a commercial ultrasonic cleaning apparatus operating at 38 or 130 kHz. Carbon black (CB) or colored oleic acid (OA) were deposited onto the PET film. The PET film was ultrasonically cleaned in an aqueous sodium chloride (NaCl) solution with or without sodium hydroxide (NaOH) or sodium dodecyl sulfate (SDS). The detergency was calculated using the microscopic image analysis system. It was found that CB detergency at 38 kHz was higher than that at 130 kHz for the same electric power. Ultrasonic washing was also carried out using PET fabrics and the detergency was evaluated by the surface reflectance method. The detergency was found to enhance in the presence of NaOH and SDS. The effect of the exposure direction of the ultrasonic wave on the fabric detergency and uneven washing was investigated using a self-developed ultrasonic cleaning apparatus operating at 38 kHz.

<p><tt>周波数38 kHz および130 kHz の市販超音波洗浄機を用いて水溶液中で超音波洗浄を行ない，周波数，洗浄液組成，および照射方向の効果を調べた．洗浄基質には，ポリエチレンテレフタレートフィルムおよびポリエステル布を用い，汚れ物質には，カーボンブラック（CB）および着色オレイン酸を使用した．洗浄液には，塩化ナトリウム（NaCl）水溶液，NaCl 水溶液に水酸化ナトリウム（NaOH）またはドデシル硫酸ナトリウム（SDS）を添加した水溶液を用いた．洗浄性評価は，フィルムは顕微鏡画像解析法，布は表面反射率法を用いた．その結果，フィルムからのCB の洗浄率は，同じ超音波出力（W）では38 kHz の方が洗浄率は高かった．布洗浄では，NaOH およびSDS の添加効果が認めら れた．さらに，38 kHz の試作超音波洗浄機を用いて照射方向を変えて布洗浄を行い，洗浄率および洗浄ムラへの影響を調べ</tt><tt>た．</tt></p>

Cleaning power of different surfactants was investigated using a model detergent system consisting of a PET film and stearic acid. Surfactants used were alcohol ethoxylates (AE, C12) and methyl ester ethoxylates (MEE, C12) with different ethylene oxide (EO) chain lengths. For comparison with these nonionic surfactants, anionic surfactant, sodium alkyl sulfate (AS, C12), was chosen. After depositing stearic acid, the PET film was cleaned in aqueous surfactant solutions by applying stirring as a mechanical action for soil removal. The amounts of stearic acid deposited on the PET film before and after the cleaning were obtained by binary processing of microscopic images of the PET film surface, from which the removal efficiency was calculated. The surface tension gamma and the contact angle on the PET film theta of the surfactant solution were measured by the pendant drop and the sessile drop method, respectively. For the nonionic surfactants, critical micelle concentration, cmc, and gamma and theta above cmc decreased with decreasing EO chain length. The removal efficiency of stearic acid increased with increasing surfactant concentration and further increase in the removal above cmc was observed in the cases of AE and MEE with EO chain length of 10. The removal efficiencies obtained in all systems had good relation with both gamma and theta, indicating that the penetration of the surfactant solution between stearic acid and the PET film in the contact zone was a dominant factor in the soil removal in the present system.

The soil removal behavior from poly(ethylene terephthalate) (PET) films was investigated using a microscopic image analysis system. Carbon black or stearic acid as a model soil was deposited onto a PET film. The PET film was cleaned in various aqueous and non-aqueous solutions by applying stirring or frequency-modulated ultrasound as a mechanical action of soil removal. The amounts of soil deposited on the PET film before and after cleaning were obtained via binary processing of microscopic images, from which the removal efficiency was calculated. Most of the carbon black was deposited on the PET film as submicron aggregates and ultrasound removed them efficiently in a short time, even for relatively smaller aggregates. The removal efficiencies with stirring were less than ca. 10% in all solutions, whereas the removal using ultrasound had high efficiencies that exceeded 80% in the surfactant-free systems. In the case of stearic acid, the removal efficiency with stirring was below 30% in the aqueous solutions, although stearic acid was removed completely in ethanol and n-decane. For ultrasonic cleaning, the removal efficiencies of stearic acid in aqueous solutions became 2-3 times as large as those with the stirring action. To improve soil release in aqueous solutions, the PET film was treated by the dry processing using an atmospheric pressure plasma jet (APPJ) equipment. The wettability and the surface free energy of the PET film were found to increase due to surface oxidation via the APPJ treatment, which resulted in enhanced removal of carbon black and stearic acid in any aqueous solutions. © 2013 by Japan Oil Chemists' Society.

The removal of the carbon black (CB) particles from the polymer substrates was investigated in water/ethanol mixtures. As substrates, the films and the fibrous assemblies of polyethylene, nylon 6 and cellulose acetate were used. The ultrasonic wave was applied as a mechanical action for cleaning. The detergency of the CB particles for the films and the fibrous assemblies was assessed with the quartz crystal microbalance (QCM) technique and the reflectometry, respectively. The detergency for the films was discussed with the wetting force calculated from the experimentally determined contact angle on the substrate and surface tension of the water/ethanol mixture.

The effect of ultraviolet light irradiation on the characteristics of the polyethylene (PE) surface was investigated by the quartz crystal microbalance (QCM) technique. The PE film was prepared on the gold electrodes of the QCM by spin-coating from the solution and then was treated by the excimer UV lamp in ambient air. The changes in the hydrophilic properties, moisture adsorption, and water retention of the PE film due to the UV irradiation were determined from the frequency change of the QCM. To evaluate the detergency of the PE film, stearic acid as model oily soil was deposited onto the PE film formed on the QCM by the Langmuir-Blodgett (LB) technique, and was ultrasonically cleaned in aqueous detergent solutions containing ethanol or surfactant. The removal efficiency obtained from the frequency change of the QCM was found to increase considerably after the UV irradiation. From independently determined contact angles and the surface free energy components of the PE film, the free energy change resulting from the penetration of the detergent solution between stearic acid and PE in the zone of contact was calculated. Good relation was found between the removal efficiency and the free energy change, indicating that the increase in the detergency of the PE surface by UV irradiation was explained by surface energetics.<br>

水晶振動子法を用いて水溶液中での固体粒子汚れの洗浄性について調べ, 表面自由エネルギーに基づいて検討を行った。洗浄基質には, 水晶振動子の金電極表面および電極にポリエチレン, ナイロン6, トリアセテートをスピンコート法により被覆した膜表面を用いた。モデル粒子汚れには, ポリエチレン粒子およびナイロン12粒子を用いた。基質への粒子の付着は, 水晶振動子を粒子分散液に垂直に浸漬する方法で行なった。分散液から基質を引き上げて空気中で乾燥した後, エタノール添加または無添加の水溶液中で粒子の洗浄を行った.洗浄率は付着前後および洗浄前後の周波数変化から算出した。洗浄率は粒子および基質により異なるが, いずれの系でもエタノールの添加により洗浄が促進された。3種類の指標液体の接触角から, 汚れおよび基質の表面自由エネルギーのLifshitz-van der Waals成分と酸一塩基成分を求めた。本研究で得られた固体粒子汚れの洗浄現象は表面自由エネルギーから算出した脱離の自由エネルギー変化により説明できることがわかった.

The titled assessment was conducted using a quartz crystal microbalance (QCM) and the Langmuir-Blodgett (LB) method. The gold electrodes of QCM were coated with cellulose acetate, nylon 6 or polyethylene film by spin-coating. Spreading monolayers of long-chain fatty acid as oily contaminants on water were transferred onto spin-coated polymer film. LB films of arachidic acid were ultrasonically cleaned in aqueous solution. Detergency was determined based on the frequency change of the QCM due to cleaning. Detergency was greatest for cellulose acetate, followed by nylon 6 and polyethylene. For all films, detergency increased with the addition of ethanol, surfactant and alkali. Detergency is discussed in relation to contact angle of aqueous solution on polymer film. Liquid introduction between LB film and the polymer surface in the zone of contact appeared to be a significant factor in the removal of LB film from the polymer surface. © 2004, Japan Oil Chemists' Society. All rights reserved.

Soil deposition on fibers was investigated from the standpoint of the waste water treatment. Polyethylene, poly (vinylidene chloride), poly (vinylidene fluoride), polyethylene terephthalate and nylon 6 fibers were used as soil collectors. Following immersion of the fibers in water from Sarusawa pond, water turbidity was measured. Turbidity decreased due to the deposition of soil onto the fiber surfaces. Poly (vinylidene chloride) fibers were more effective as a soil collector than any other fibers.<BR>Particle deposition from an aqueous solution was investigated using a model system consisting of spherical polyethylene or nylon particles and a polymeric plate. The plate was perpendicularly immersed in an aqueous suspension. The number of particles deposited on the plate appeared related to the polar components of surface free energies of the particle and plate. The results of particle deposition in the model system were in good agreement with those in systems using water from a pond.

Adhesion and removal phenomena in aqueous solutions were investigated using spherical polyethylene particles and a quartz plate. The experimental results are discussed and explained on the basis of the heterocoagulation theory, using ζ-potentials of the particles and the quartz plate as determined by micro-electrophoresis. The magnitude of the energy barrier preventing particle adhesion was found to be about 4000 κT for particles of 4-5μm in diameter. The Hamaker constant (A₁₁) of a polyethylene particle was estimated by the adhesion and removal phenomena and was determined as 6.06.8×10^-13ergs from curves of interaction energy plotted against separation.