谷口 省吾, 尾崎 博明, 山田 修, Rabindra Raj Giri
環境工学研究論文集, 44 299-305, Nov, 2007 Peer-reviewed
This paper aimed to elucidate electrochemical degradations of sixteen common pharmaceuticals and personal care products (PPCPs)(Fenoprofen, Ibuprofen, Ketoprofen, Phenacetine, Naproxen, Indomethacin, Diclofenac, Isopropylantiprine, Clarithromycin, Gemfibrozil, Clofibric acid, Carbamazepine, Phenytoin, Phenobarbital, Methoxsalen and Triclosan) using newly developed porous ceramic electrodes in presence of sodium chloride by laboratory batch experiments. Based on their degradations, the PPCPs were classified into three groups: easily degradable (Isopropylantipyrine, Diclofenac, Naproxen, Indomethacin, Triclosan and Gemfibrozil), degradable in relatively longer time (Phenacetine, Clarithromycin, Methoxsalen and Carbamazepine) and difficult to degrade (Ibuprofen, Ketoprofen, Phenobarbital, Clofibric acid, Phenytoin and Fenoprofen). Adsorption of the PPCPs on electrodes was an important phenomenon. The values for Triclosan; Indomethacin, Clarithromycin and Methoxsalen; and others were about 100%, 30% and less than 20%, respectively. Though free chloride species played an important role on PPCPs removals, the degradations due to free chloride only were significantly smaller than the degradations by electrochemical process. Based on the results of this investigation, it is concluded that electrochemical process with the new porous ceramic electrodes is an efficient and promising oxidation method for PPCPs.